Let $Pf = \mathbb{E}f$ denote the integration of random variable $f$ under probability measure $P$.
Empirical measure (empirical probability density function, EPDF) is the discrete uniform measure on a random sample; that is, each observation of the sample is assigned the same finite probability. Empirical measure is a random measure because it is dependent on a random sample. Symbolically, the empirical measure $P_n$ of a measurable set $A$ in sample space $(Ω,Σ)$ is defined as \[ P_n(A) = \frac{1}{n} \sum_{i=1}^n \mathbf{1}_A(X_i) \]
The empirical distribution function (ECDF) of a real-valued random variable is the empirical measure indexed by a class of one-sided intervals: \[ P_n(x) = P_n (-\infty,x] = \frac{1}{n} \sum_{i=1}^n \mathbf{1}(X_i \leq x) \]
Empirical distribution functions have the following properties (point-wise in the parameter domain):
Theorem: (Glivenko-Cantelli) Empirical distribution function converges uniformly to the population distribution function: \[ \| P_n - F \|_{\infty} \overset{a.s.}{\to} 0 \]
For a parameter $\mathbf{h}(P \mathbf{g}(X))$ that is a function of expectations, its method-of-moments estimator (substitution estimator) {Pearson1894} replaces the population measure with the empirical measure: \( \mathbf{h}(P_n \mathbf{g}(X)) \). If the parameter to be estimated is a function of moments, $h(PX, \cdots, PX^k)$, the method-of-moments estimator is \( h( P_n X, \cdots, P_n X^k) \).
Empirical moments are consistent and asymptotically normal: using central limit theorem, we can show that \[ \sqrt{n} [ (P_n X, \cdots, P_n X^k) - (P X, \cdots, P X^k) ] \Rightarrow N(0,Σ) \], where \( Σ_{ij} = P X^{i+j} - P X^i P X^j \). If $h(\cdot)$ is continuously differentiable at $(PX, \cdots, PX^k)$, by the Delta method, we have \[ \sqrt{n} [ h( P_n X, \cdots, P_n X^k) - h(PX, \cdots, PX^k) ] \Rightarrow N(0, (∇h)'Σ(∇h)) \], where $∇h$ is evaluated at $(PX, \cdots, PX^k)$.
For Gamma distribution $Γ(α, β)$:
For uniform distribution $U(0, θ)$, because $θ = 2 PX$, its method of moments estimator is $2 P_n X$. But this estimator is not very efficient.